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- Nachgewiesen in: USPTO Patent Applications
- Sprachen: English
- Document Number: 20240024819
- Publication Date: January 25, 2024
- Appl. No: 18/256370
- Application Filed: December 03, 2021
- Claim: 1-21. (canceled)
- Claim: 22. A catalytic device for the removal of nitrogen oxides and ammonia from the exhaust gas of lean-burn combustion engines, comprising: a) an upstream SCR catalyst comprising i) a carrier substrate, and ii) a first washcoat comprising a first SCR catalytically active composition SCRfirst and optionally at least one first binder, wherein the first washcoat is applied to the carrier substrate, b) a downstream ASC catalyst comprising i) a carrier substrate, and ii) a bottom layer comprising a third washcoat comprising an oxidation catalyst and optionally at least one third binder, said bottom layer being applied directly onto the carrier substrate, and iii) a top layer comprising a second washcoat comprising a second SCR catalytically active composition SCRsecond and optionally at least one second binder and, said top layer being applied onto the bottom layer, wherein the upstream SCR catalyst and the downstream ASC catalyst are present on a single carrier substrate or on two different carrier substrates, the first and the second SCR catalytically active compositions are the same or different from one another, the optionally comprised at least one first, second and third binders are the same or different from one another, and the ratio [mathematical expression included] of the loadings of the first and the second SCR catalytically active compositions, given in g/L, in the first and the second washcoat is 1.2:1 to 2:1.
- Claim: 23. The catalytic device according to claim 22, wherein the first and the second SCR catalytically active composition are, independently from one another, selected from molecular sieves.
- Claim: 24. The catalytic device according to claim 23, wherein the molecular sieves are crystalline aluminosilicate zeolites selected from ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, BEA, BIK, CDO, CHA, DDR, DFT, EAB, EDI, EPI, ERI, ESV, ETL, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, RTH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG, ZON and mixtures and intergrowths that contain at least one of these framework types.
- Claim: 25. The catalytic device according to claim 24, wherein the crystalline aluminosilicate zeolites have a SAR value of 5 to 100.
- Claim: 26. The catalytic device according to claim 24, wherein the crystalline aluminosilicate zeolites are promoted with copper, and wherein the copper to aluminum atomic ratio is in the range of between 0.005 to 0.555.
- Claim: 27. The catalytic device according to claim 24, wherein the aluminosilicate zeolites are promoted with iron, and wherein the iron to aluminum atomic ratio is in the range of between 0.005 to 0.555.
- Claim: 28. The catalytic device according to claim 24, wherein the aluminosilicate zeolites are promoted with both copper and iron, and wherein the (Cu+Fe):Al atomic ratio is in the range of between 0.005 to 0.555.
- Claim: 29. The catalytic device according to claim 22, wherein the oxidation catalyst comprises a platinum group metal, a platinum group metal oxide, a mixture of two or more platinum group metals, a mixture of two or more platinum group metal oxides, or a mixture of at least one platinum group metal and at least one platinum group metal oxide, wherein the platinum group metal is selected from ruthenium, rhodium, palladium, iridium and platinum.
- Claim: 30. The catalytic device according to claim 22, wherein the first, second and third binder are, independently from one another, selected from alumina, silica, non-zeolitic silica-alumina, naturally occurring clay, TiO2, ZrO2, CeO2, SnO2 and mixtures and combinations thereof.
- Claim: 31. The catalytic device according to claim 22, wherein the washcoat loading of the first SCR catalytically active composition is between 100 and 230 g/L, and the washcoat loading of the second SCR catalytically active composition is between 70 and 170 g/L, under the proviso that the ratio [mathematical expression included] of the loadings of the first and the second SCR catalytically active compositions, given in g/L, in the first and the second washcoat is between 1.2:1 to 2:1.
- Claim: 32. The catalytic device according to claim 22, wherein the washcoat loading of the third washcoat is between 10 and 100 g/L, and the platinum group metal concentration within the third washcoat is between 0.5 and 25 g/ft3.
- Claim: 33. The catalytic device according to claim 22, wherein the upstream SCR catalyst and the downstream ASC catalyst are present as two adjacent zones on one single carrier substrate, the upstream SCR catalyst extends on an axial length of the carrier substrate from the upstream end to 40 to 80% of the entire length of the carrier substrate, the downstream ASC catalyst extends on an axial length of the carrier substrate from the downstream end to 40 to 80% of the entire length of the carrier substrate, and there is substantially no overlap nor a gap between the SCR catalyst zone and the ASC catalyst zone, and the lengths of both zones account for 100% of the total axial length of the carrier.
- Claim: 34. The catalytic device according to claim 33, wherein the carrier substrate is selected from ceramic, metallic and corrugated carrier substrates.
- Claim: 35. The catalytic device according to claim 34, wherein the carrier substrate is a ceramic carrier substrate selected from flow-through carrier substrates and wall-flow filters.
- Claim: 36. The catalytic device according to claim 22, wherein the upstream SCR catalyst and the downstream ASC catalyst are present on two different carrier substrates which are immediately adjacent to one another.
- Claim: 37. The catalytic device according to claim 36, wherein the carrier substrates are, independently from one another, selected from ceramic, metallic and corrugated carrier substrates.
- Claim: 38. The catalytic device according to claim 37, wherein the carrier substrates are ceramic carrier substrate which are selected, independently from one another, from flowthrough carrier substrates and wall-flow filters.
- Claim: 39. A system for the removal of nitrogen oxides and ammonia from the exhaust gas of lean-burn combustion engines, comprising: a) means for injecting ammonia or an ammonia precursor solution into the exhaust stream, b) a catalytic device according to claim 22 arranged immediately downstream of the means for injecting ammonia or an ammonia precursor solution according to a).
- Claim: 40. The system for the removal of nitrogen oxides and ammonia from the exhaust gas of lean-burn combustion engines according to claim 39, further comprising an oxidation catalyst for the oxidation of volatile organic compounds, carbon monoxide and hydrocarbons, said catalyst being located directly upstream of the means for injecting ammonia or an ammonia precursor solution into the exhaust system.
- Claim: 41. The system for the removal of nitrogen oxides and ammonia from the exhaust gas of lean-burn combustion engines according to claim 39, further comprising a filter for the removal of particulate matter, said filter being located immediately downstream of the oxidation catalyst and immediately upstream of the means for injecting ammonia or an ammonia precursor solution into the exhaust stream.
- Claim: 42. A method of removing nitrogen oxides and ammonia from an exhaust gas of a lean-burn combustion engine, which comprises passing the exhaust gas through the catalytic device according to claim 22.
- Current International Class: 01; 01; 01; 01; 01; 01; 01; 01; 01; 01; 01
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