Synthesis and characterization of Na3PS4 and Na 2.85 P 0.85 W 0.15 S 4 as solid electrolytes
In: Symposium UGA-ESRF ; https://hal.science/hal-04189945 ; Symposium UGA-ESRF, May 2023, Grenoble, France, 2023
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Zugriff:
International audience ; The next generations of postlithium systems are already under development. These hold the promise of overcoming some of the remaining challenges associated with current lithium-ion battery technology related to safety, the need for scarce resources and their environmental impacts. Na₃PS₄ (NPS) is a sodium superionic conductor that crystallizes in the I-43m space group and reaches ionic conductivities in the range of the mS/cm. • X-ray diffractograms show a cubic crystalline phase of Na3PS4 and a mixture of Na3PS4 and WS2 for the Na2.85P0.85W0.15S4 sample.• SEM-EDX results confirmed that a reaction occurs between the sample holder (Macor®) and the solid electrolytes during the heat treatments.• Electrochemical results show that a heat treatment under Ar slightly improves the ionic conductivity for the NPS sample, while the HTs in presence of Macor® spacer turn the materials into ionic insulants.
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Synthesis and characterization of Na3PS4 and Na 2.85 P 0.85 W 0.15 S 4 as solid electrolytes
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Autor/in / Beteiligte Person: | Iles, Alisson, A ; Mirolo, Marta ; Mayer, Sergio, Federico ; European Synchrotron Radiation Facility Grenoble (ESRF) ; Matériaux Interfaces ELectrochimie (MIEL) ; Laboratoire d'Electrochimie et de Physico-chimie des Matériaux et des Interfaces (LEPMI) ; Institut de Chimie - CNRS Chimie (INC-CNRS)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ) ; Université Grenoble Alpes (UGA)-Institut de Chimie - CNRS Chimie (INC-CNRS)-Université Savoie Mont Blanc (USMB Université de Savoie Université de Chambéry )-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ) ; Université Grenoble Alpes (UGA) ; UGA-ESRF |
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Zeitschrift: | Symposium UGA-ESRF ; https://hal.science/hal-04189945 ; Symposium UGA-ESRF, May 2023, Grenoble, France, 2023 |
Veröffentlichung: | HAL CCSD, 2023 |
Medientyp: | Konferenz |
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