Crystal Structure, Solid‐State NMR Spectroscopic and Photoluminescence Studies of Organic‐Inorganic Hybrid Materials (HL) 6 [Ge 6 (OH) 6 (hedp) 6 ]·2(L)· H 2 O, L = hqn or phen (Eur. J. Inorg. Chem. 23/2006)
In: European Journal of Inorganic Chemistry, Jg. 2006 (2006), Heft 23, S. 4709-4709
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Zugriff:
The cover picture shows the three‐dimensional supramolecular arrangement of 1,10‐phenanthroline (phen) residues in compound (Hphen) 6 [Ge 6 (OH) 6 (hedp) 6 ]·2(phen)·20H 2 O (where H 4 hedp stands for etidronic acid). Protonated organic residues, Hphen + , π‐π‐stack along the [101] direction of the unit cell, which leads to the formation of columns that are interconnected through a series of weak C–H···π interactions with neighbouring 1,10‐phenanthrolines. The resulting organic framework is highly porous and contains charge‐balancing centrosymmetric hexameric anionic [Ge 6 (ν 2 ‐OH) 6 (C 2 H 4 O 7 P 2 ) 6 ] 6– moieties within the channels and a large number of highly disordered water molecules (total available volume of ca. 2462 Å 3 per unit cell). Details are discussed in the article by J. Rocha et al. on p. 4741 ff.
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Crystal Structure, Solid‐State NMR Spectroscopic and Photoluminescence Studies of Organic‐Inorganic Hybrid Materials (HL) 6 [Ge 6 (OH) 6 (hedp) 6 ]·2(L)· H 2 O, L = hqn or phen (Eur. J. Inorg. Chem. 23/2006)
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Autor/in / Beteiligte Person: | Mafra, Luís ; Almeida Paz, Filipe E. ; Shi, Fa‐Nian ; Sá Ferreira, Rute A. ; Carlos, Luís D. ; Trindade, Tito ; Fernandez, Christian ; Klinowski, Jacek ; Rocha, João |
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Zeitschrift: | European Journal of Inorganic Chemistry, Jg. 2006 (2006), Heft 23, S. 4709-4709 |
Veröffentlichung: | Wiley, 2006 |
Medientyp: | academicJournal |
ISSN: | 1434-1948 |
DOI: | 10.1002/ejic.200690047 |
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