Synthesis, characterization, and thermal properties of N,N,N′,N′-tetramethyl guanidinium tribromidocadmate(II) exhibiting an unusual coordination geometry
In: ISSN: 0792-1241, 2017
academicJournal
Zugriff:
International audience ; The reaction of N,N,N′,N′-tetramethyl guanidine, NHC(N(CH3)2)2 (TMGD) and CdBr2·4H2O in ethanol led to the formation of [TMGDH][CdBr3] (1), which crystallizes in the monoclinic space group Cc with Z=4, a=8.9079(7) Å, b=18.5810(14) Å, c=8.1637(6) Å, β=107.953(3)°, and V=1285.44(17) Å3. In the crystal lattice, 1 is organized in one-dimensional anionic chains of CdBr4 tetrahedra sharing two corners. To our knowledge, this is the first evidence of such a coordination geometry described for a bromocadmate derivative. The negative charges are compensated by monoprotonated N,N,N′,N′-tetramethyl guanidinium cations (TMGDHs), which are in N-H hydrogen bonding interaction with the terminal bromide atoms of the anionic chain. The title compound was also characterized by middle and far-infrared spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The elemental analysis corroborates as well the X-ray elucidation. Multinuclear solution nuclear magnetic resonance (NMR) spectroscopic measurements (1H, 13C{1H}) were conducted in D2O.
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Synthesis, characterization, and thermal properties of N,N,N′,N′-tetramethyl guanidinium tribromidocadmate(II) exhibiting an unusual coordination geometry
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Autor/in / Beteiligte Person: | Ndiaye, Mamadou ; Samb, Abdoulaye ; Diop, Libasse ; Cattey, Hélène ; Pourchet, Sylvie ; Plasseraud, Laurent ; Laboratoire des Produits Naturels Université Cheikh Anta Diop, Dakar ; Université Cheikh Anta Diop Dakar, Sénégal (UCAD) ; Laboratoire de Chimie Minérale et Analytique (LACHIMIA) ; Institut de Chimie Moléculaire de l'Université de Bourgogne Dijon (ICMUB) ; Université de Bourgogne (UB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
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Zeitschrift: | ISSN: 0792-1241, 2017 |
Veröffentlichung: | HAL CCSD ; De Gruyter, 2017 |
Medientyp: | academicJournal |
DOI: | 10.1515/mgmc-2017-0028 |
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