STRUCTURAL AND IMPEDANCE CHARACTERISTICS OF KPb<subscript>2</subscript>V<subscript>5</subscript>O<subscript>15</subscript>.

The polycrystalline sample of KPb 2 V 5 O 15 was prepared by a mixed-oxide method relatively at low temperature (i.e., 550°C). X-ray diffraction studies of the compound showed the formation of single phase orthorhombic crystal structure at room temperature. SEM micrograph showed the homogeneous distribution of grains throughout the sample. Electric properties were analyzed using the complex impedance spectroscopy. The modulus plot showed the presence of both the grain and grain boundary effect. The bulk impedance evaluated from the Nyquist plots was observed to decrease with the rise in temperature, showing a negative temperature coefficient of resistance. The variation of AC electrical conductivity (σ AC ) was measured in a wide temperature (30-500°C) and frequency (10 2 -10 6 Hz) range. The activation energy of the compound calculated from both the impedance and modulus spectrum was found to be the same. [ABSTRACT FROM AUTHOR]

Copyright of International Journal of Modern Physics B: Condensed Matter Physics; Statistical Physics; Applied Physics is the property of World Scientific Publishing Company and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)