Guanidinium-based dicarboxylic acid ionic liquids for SO<subscript>2</subscript> capture.
In: Journal of Chemical Technology & Biotechnology, Jg. 92 (2017-04-01), Heft 4, S. 767-774
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Zugriff:
BACKGROUND Ionic liquids ( ILs) have been widely used in the field of SO 2 separation for gases. In this study, two kinds of guanidinium-based dicarboxylic acid ionic liquids including [1,1,3,3-tetramethylguanidinium][Poly(ethylene glycol) bis(carboxymethyl) ether] ([ TMG][ PBE]) and [1,1,3,3-tetramethylguanidinium] [Suberic acid] ([ TMG][ SUB]) were synthesized, and their absorption and desorption performance of SO 2 were investigated. RESULTS The saturated molar ratio of SO 2 to [ TMG][ PBE] and [ TMG][ SUB] were 8.74 and 5.96 mol SO 2 per mole ILs at 25 °C, respectively. [ TMG][ PBE] saturated with SO 2 was easier to desorb and could be recycled at least 5 times without loss of initial performance, while the ability to absorb SO 2 by [ TMG][ SUB] was gradually weakened after desorption. The absorption mechanism is discussed. Results showed that SO 2 could interact not only with the amino group on the cation but also with the methylene bonded to the carbonyl carbon on the anion for [ TMG][ SUB]. As for [ TMG][ PBE], SO 2 could interact with the ether group by S-O ligand interaction, instead of interacting with the methylene group bonded to the carbonyl carbon on the anion. [ TMG][ PBE] show good performance for SO 2 capture. CONCLUSION The anion of dicarboxylic acid-based ILs plays an important role in absorption/desorption of SO 2 on the basis of the experimental results. © 2016 Society of Chemical Industry [ABSTRACT FROM AUTHOR]
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Titel: |
Guanidinium-based dicarboxylic acid ionic liquids for SO<subscript>2</subscript> capture.
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Autor/in / Beteiligte Person: | Meng, Xiaocai ; Wang, Jianying ; Jiang, Haichao ; Zhang, Xiangjing ; Liu, Shuolei ; Hu, Yongqi |
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Zeitschrift: | Journal of Chemical Technology & Biotechnology, Jg. 92 (2017-04-01), Heft 4, S. 767-774 |
Veröffentlichung: | 2017 |
Medientyp: | academicJournal |
ISSN: | 0268-2575 (print) |
DOI: | 10.1002/jctb.5052 |
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