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As a result of full-scale ongoing global efforts, the power conversion efficiency (PCE) of the organic-inorganic metal halide perovskite has skyrocketed. Unfortunately, the long-term operational stability for commercialization standards is still lagging owing to intrinsic defects such as ion migration-induced degradation, undercoordinated Pb 2+ , and shallow defects initiated by disordered crystal growth. Herein, we employed multifunctional, non-volatile tetra-methyl guanidine hydrochloride [TMGHCL] ionic liquid (IL) as an additive to elucidate defects' passivation effects on organic-inorganic metal halide perovskite. More specifically, the formation of hydrogen bonds between H + in GA + and I - and coordinate bonding between Cl - and undercoordinated Pb 2+ could significantly passivate these defects. The hypothesis was confirmed by both experimental and DFT simulations displaying that the optimized ratio of IL integration restrains ion migration, improving grains' size, and significantly elongating the carrier lifetime. Remarkably, the modified cell achieved a peak efficiency of 22.00 % with negligible hysteresis, compared to the control device's PCE of 20.12 %. In addition, the TMGHCL-based device retains its 93.29 % efficiency after 16 days of continuous exposure to air with a relative humidity of 35±5% and temperature of 25±5 °C. This efficient approach of adding IL to perovskites absorber can produce high PCE and has strong commercialization potential.

Titel:	Revealing the Roles of Guanidine Hydrochloride Ionic Liquid in Ion Inhibition and Defects Passivation for Efficient and Stable Perovskite Solar Cells.
Autor/in / Beteiligte Person:	Saeed, A ; Wang, L ; Chen, Z ; Fang, J ; Hussain, I ; Yuan, L ; Wang, S ; Zhao, J ; Zhang, H ; Miao, Q
Link:	Zum Volltext
Zeitschrift:	ChemSusChem, 2024-05-10, S. e202400466
Veröffentlichung:	Ahead of Print, 2024
Medientyp:	academicJournal
ISSN:	1864-564X (electronic)
DOI:	10.1002/cssc.202400466
Sonstiges:	Nachgewiesen in: MEDLINE Sprachen: English Publication Type: Journal Article Language: English [ChemSusChem] 2024 May 10, pp. e202400466. <i>Date of Electronic Publication: </i>2024 May 10. References: S. Zhang, H. Si, W. Fan, M. Shi, M. Li, C. Xu, Z. Zhang, Q. Liao, A. Sattar, Z. Kang, Y. Zhang, Angew. Chem. Int. Ed. 2020, 59, 11573–11582. ; . ; J. J. Yoo, G. Seo, M. R. Chua, T. G. Park, Y. Lu, F. Rotermund, Y.-K. Kim, C. S. Moon, N. J. Jeon, J.-P. Correa-Baena, V. Bulović, S. S. Shin, M. G. Bawendi, J. Seo, Nature 2021, 590, 587–593;. ; H. Min, D. Y. Lee, J. Kim, G. Kim, K. S. Lee, J. Kim, M. J. Paik, Y. K. Kim, K. S. Kim, M. G. Kim, T. J. Shin, S. Il Seok, Nature 2021, 598, 444–450;. ; N. J. Jeon, J. H. Noh, W. S. Yang, Y. C. Kim, S. Ryu, J. Seo, S. I. Seok, Nature 2015, 517, 476–480. ; Y. Zhao, H. Tan, H. Yuan, Z. Yang, J. Z. Fan, J. Kim, O. Voznyy, X. Gong, L. N. Quan, C. S. Tan, J. Hofkens, D. Yu, Q. Zhao, E. H. Sargent, Nat. Commun. 2018, 9, 1607. ; . ; G. Li, J. Song, J. Wu, Y. Xu, C. Deng, Z. Song, X. Wang, Y. Du, Q. Chen, R. Li, W. Sun, Z. Lan, Chem. Eng. J. 2022, 449, 137806;. ; M. H. Alotaibi, Y. A. Alzahrani, N. Arora, A. Alyamani, A. Albadri, H. Albrithen, I. H. Al-Lehyani, S. M. Alenzi, A. Z. Alanzi, F. S. Alghamdi, S. M. Zakeeruddin, S. Meloni, M. I. Dar, M. Graetzel, Solar RRL 2020, 4, 1900234. ; M. Wang, S. Tan, Y. Zhao, P. Zhu, Y. Yin, Y. Feng, T. Huang, J. Xue, R. Wang, G. S. Han, H. S. Jung, J. Bian, J.-W. Lee, Y. Yang, Adv. Funct. Mater. 2021, 31, 2007520. ; C. Li, X. Wang, E. Bi, F. Jiang, S. M. Park, Y. Li, L. Chen, Z. Wang, L. Zeng, H. Chen, Y. Liu, C. R. Grice, A. Abudulimu, J. Chung, Y. Xian, T. Zhu, H. Lai, B. Chen, R. J. Ellingson, F. Fu, D. S. Ginger, Z. Song, E. H. Sargent, Y. Yan, Science 2023, 379, 690–694. ; J. Zhao, S. O. Fürer, D. P. McMeekin, Q. Lin, P. Lv, J. Ma, W. L. Tan, C. Wang, B. Tan, A. S. R. Chesman, H. Yin, A. D. Scully, C. R. McNeill, W. Mao, J. Lu, Y.-B. Cheng, U. Bach, Energy Environ. Sci. 2023, 16, 138–147. ; . ; J. Kim, M. I. Saidaminov, H. Tan, Y. Zhao, Y. Kim, J. Choi, J. W. Jo, J. Fan, R. Quintero-Bermudez, Z. Yang, L. N. Quan, M. Wei, O. Voznyy, E. H. Sargent, Adv. Mater. 2018, 30, 1706275;. ; T. Bu, J. Li, Q. Lin, D. P. McMeekin, J. Sun, M. Wang, W. Chen, X. Wen, W. Mao, C. R. McNeill, W. Huang, X.-L. Zhang, J. Zhong, Y.-B. Cheng, U. Bach, F. Huang, Nano Energy 2020, 75, 104917;. ; S. Liu, Y. Guan, Y. Sheng, Y. Hu, Y. Rong, A. Mei, H. Han, Adv. Energy Mater. 2020, 10, 1902492. ; . ; M. He, X. Pang, X. Liu, B. Jiang, Y. He, H. Snaith, Z. Lin, Angew. Chem. Int. Ed. 2016, 55, 4280–4284;. ; Y. Lao, S. Yang, W. Yu, H. Guo, Y. Zou, Z. Chen, L. Xiao, Adv. Sci. 2022, 9, 2105307;. ; X. Deng, L. Xie, S. Wang, C. Li, A. Wang, Y. Yuan, Z. Cao, T. Li, L. Ding, F. Hao, Chem. Eng. J. 2020, 398, 125594. ; Y. Wang, Y. Yang, N. Li, M. Hu, S. R. Raga, Y. Jiang, C. Wang, X.-L. Zhang, M. Lira-Cantu, F. Huang, Y.-B. Cheng, J. Lu, Adv. Funct. Mater. 2022, 32, 2204396. ; X. Zhu, M. Du, J. Feng, H. Wang, Z. Xu, L. Wang, S. Zuo, C. Wang, Z. Wang, C. Zhang, X. Ren, S. Priya, D. Yang, S. Liu, Angew. Chem. Int. Ed. 2021, 60, 4238–4244. ; Y. Wan, S. Dong, Y. Wang, L. Yang, W. Qin, H. Cao, C. Yao, Z. Ge, S. Yin, RSC Adv. 2016, 6, 97848–97852. ; D. Liu, Z. Shao, J. Gui, M. Chen, M. Liu, G. Cui, S. Pang, Y. Zhou, Chem. Commun. 2019, 55, 11059–11062. ; D. He, T. Zhou, B. Liu, L. Bai, W. Wang, H. Yuan, C. Xu, Q. Song, D. Lee, Z. Zang, L. Ding, J. Chen, EcoMat 2022, 4, e12158. ; N. De Marco, H. Zhou, Q. Chen, P. Sun, Z. Liu, L. Meng, E.-P. Yao, Y. Liu, A. Schiffer, Y. Yang, Nano Lett. 2016, 16, 1009–1016. ; S. Bai, P. Da, C. Li, Z. Wang, Z. Yuan, F. Fu, M. Kawecki, X. Liu, N. Sakai, J. T.-W. Wang, S. Huettner, S. Buecheler, M. Fahlman, F. Gao, H. J. Snaith, Nature 2019, 571, 245–250. ; Y. Kong, W. Shen, H. Cai, W. Dong, C. Bai, J. Zhao, F. Huang, Y.-B. Cheng, J. Zhong, Adv. Funct. Mater. 2023, n/a, 2300932. ; A. D. Jodlowski, C. Roldán-Carmona, G. Grancini, M. Salado, M. Ralaiarisoa, S. Ahmad, N. Koch, L. Camacho, G. de Miguel, M. K. Nazeeruddin, Nat. Energy 2017, 2, 972–979. ; . ; Y. Huang, Y. Li, E. L. Lim, T. Kong, Y. Zhang, J. Song, A. Hagfeldt, D. Bi, J. Am. Chem. Soc. 2021, 143, 3911–3917;. ; N. D. Pham, V. T. Tiong, D. Yao, W. Martens, A. Guerrero, J. Bisquert, H. Wang, Nano Energy 2017, 41, 476–487. ; Z. Li, L. Hao, D. Liu, X. Sun, Q. Zhao, Z. Shao, C. Chen, X. Wang, L. Wang, G. Cui, S. Pang, Solar RRL 2022, 6, 2200003. ; Y. Liu, Y. Gao, M. Lu, Z. Shi, W. W. Yu, J. Hu, X. Bai, Y. Zhang, Chem. Eng. J. 2021, 426, 130841. ; D. Wei, H. Huang, P. Cui, J. Ji, S. Dou, E. Jia, S. Sajid, M. Cui, L. Chu, Y. Li, B. Jiang, M. Li, Nanoscale 2019, 11, 1228–1235. ; . ; J. Qi, H. Xiong, C. Hou, Q. Zhang, Y. Li, H. Wang, Nanoscale 2020, 12, 3646–3656;. ; J. Wu, J. Shi, Y. Li, H. Li, H. Wu, Y. Luo, D. Li, Q. Meng, Adv. Energy Mater. 2019, 9, 1901352. ; Y. Zhong, J. Yang, X. Wang, Y. Liu, Q. Cai, L. Tan, Y. Chen, Adv. Mater. 2023, n/a, 2302552. ; . ; Z. Wu, M. Jiang, Z. Liu, A. Jamshaid, L. K. Ono, Y. Qi, Adv. Energy Mater. 2020, 10, 1903696;. ; Y. Zhang, N.-G. Park, Adv. Funct. Mater. 2023, n/a, 2308577. ; F. Li, X. Deng, Z. Shi, S. Wu, Z. Zeng, D. Wang, Y. Li, F. Qi, Z. Zhang, Z. Yang, S.-H. Jang, F. R. Lin, S. W. Tsang, X.-K. Chen, A. K. Y. Jen, Nat. Photonics 2023, 17, 478–484. ; X. Zhu, S. Yang, Y. Cao, L. Duan, M. Du, J. Feng, Y. Jiao, X. Jiang, Y. Sun, H. Wang, S. Zuo, Y. Liu, S. Liu, Adv. Energy Mater. 2022, 12, 2103491. ; . ; S. Cao, H. Wang, H. Li, J. Chen, Z. Zang, Chem. Eng. J. 2020, 394, 124903;. ; W. Zhang, Y. Li, X. Liu, D. Tang, X. Li, X. Yuan, Chem. Eng. J. 2020, 379, 122298. ; Z. Chen, L. Wang, J. Fang, A. Saeed, K. Wang, Q. Miao, ACS Appl. Energ. Mater. 2023, 6, 8489–8494. ; Y. Miao, Z. Wang, C. Chen, X. Ding, M. Zhai, L. Liu, Z. Xia, H. Wang, M. Cheng, Sol. RRL 2022, 6, 2200364. ; . ; G. Kresse, J. Furthmüller, Physical review. B, Condens. Matter 1996, 54, 11169–11186;. ; G. García-Calderón, A. Rubio, J. Villavicencio, Phys. Rev. A 1999, 59, 1758–1761. ; J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865–3868. ; . ; S. Grimme, J. Antony, S. Ehrlich, H. Krieg, J. Chem. Phys. 2010, 132, 154104;. ; S. Grimme, S. Ehrlich, L. Goerigk, J. Comput. Chem. 2011, 32, 1456–1465. ; . ; G. J. Martyna, M. L. Klein, M. Tuckerman, J. Chem. Phys. 1992, 97, 2635–2643;. ; W. G. Hoover, Phys. Rev. A 1985, 31, 1695–1697. ; T. K. Woo, P. M. Margl, P. E. Blöchl, T. Ziegler, J. Phys. Chem. B 1997, 101, 7877–7880. Grant Information: 22078340 National Natural Science Foundation of China; 21878309 National Natural Science Foundation of China; 2019049 Youth Innovation Promotion Association, Chinese Academy of Sciences (CAS); 2024145 CAS Henan Industrial Technology Innovation & Incubation Center; E2019103008 Natural Science Foundation of Hebei Province; GJHZ1321 CAS-TWAS Centre of Excellence for Green Technology; ANSO-PA-2020-08 International Green Technology Association Contributed Indexing: Keywords: Enhanced Performance; Guanidium Ionic Liquid; Ion immobilization; Perovskites solar cells; Stability Entry Date(s): Date Created: 20240510 Latest Revision: 20240607 Update Code: 20240607

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Revealing the Roles of Guanidine Hydrochloride Ionic Liquid in Ion Inhibition and Defects Passivation for Efficient and Stable Perovskite Solar Cells.