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Covalent Organic Frameworks (COFs) are crystalline, porous organic materials. Recent studies have demonstrated novel processing strategies for COFs to form adaptable architectures, but these have focused primarily on imine-linked COFs. This work presents a new synthesis and processing route to produce crystalline hydrazone-linked COF gels and aerogels with hierarchical porosity. The method was implemented to produce a series of hydrazone-linked COFs with different alkyl side-chain substituents, achieving control of the hydrophilicity of the final aerogel. Variation in the length of the alkyl substituents yielded materials with controllable form factors that can preferentially adsorb water or nonpolar organic solvents. Additionally, a method for additive manufacturing of hydrazone-linked COFs using hydroxymethylcellulose as a sacrificial additive is presented. This work demonstrates an effective and simple approach to the fabrication of hydrazone COF aerogels and additive manufacturing to produce hydrazone COFs of desired shape.

Titel:	Synthesis and Additive Manufacturing of Hydrazone-Linked Covalent Organic Framework Aerogels.
Autor/in / Beteiligte Person:	Ajnsztajn, A ; Harikrishnan, VVJ ; Alahakoon, SB ; Zhu, D ; Barnes, M ; Daum, J ; Gayle, J ; Tomur, G ; Lowenstein, J ; Roy, S ; Ajayan, PM ; Verduzco, R
Link:	Zum Volltext
Zeitschrift:	Chemistry (Weinheim an der Bergstrasse, Germany), Jg. 29 (2023-12-01), Heft 67, S. e202302304
Veröffentlichung:	Weinheim, Germany : Wiley-VCH, 2023
Medientyp:	academicJournal
ISSN:	1521-3765 (electronic)
DOI:	10.1002/chem.202302304
Sonstiges:	Nachgewiesen in: MEDLINE Sprachen: English Publication Type: Journal Article Language: English [Chemistry] 2023 Dec 01; Vol. 29 (67), pp. e202302304. <i>Date of Electronic Publication: </i>2023 Oct 17. References: C. S. Diercks, O. M. Yaghi, Science 2017, 355, eaal1585. ; R. Liu, K. T. Tan, Y. Gong, Y. Chen, Z. Li, S. Xie, T. He, Z. Lu, H. Yang, D. Jiang, Chem. Soc. Rev. 2021, 50, 120-242. ; R. P. Bisbey, W. R. Dichtel, ACS Cent. Sci. 2017, 3, 533-543. ; K. T. Tan, S. Ghosh, Z. Wang, F. Wen, D. Rodríguez-San-Miguel, J. Feng, N. Huang, W. Wang, F. Zamora, X. Feng, A. Thomas, D. Jiang, Nat. Rev. Methods Primer 2023, 3, 1-19. ; K. Geng, T. He, R. Liu, S. Dalapati, K. T. Tan, Z. Li, S. Tao, Y. Gong, Q. Jiang, D. Jiang, Chem. Rev. 2020, 120, 8814-8933. ; D. Zhu, G. Xu, M. Barnes, Y. Li, C.-P. Tseng, Z. Zhang, J.-J. Zhang, Y. Zhu, S. Khalil, M. M. Rahman, R. Verduzco, P. M. Ajayan, Adv. Funct. Mater. 2021, 31, 2100505. ; X. Zhao, P. Pachfule, A. Thomas, Chem. Soc. 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Grant Information: C-2124 Welch Foundation; FA9550-21-1-0460 US Air Force Office of Scientific Research; FA9550-21-1-0460 Clarkson Aerospace Corporation; CHE-2247729 Division of Chemistry Contributed Indexing: Keywords: 3D printing; adsorbents; covalent organic framework; gelation; processing Entry Date(s): Date Created: 20230904 Latest Revision: 20231201 Update Code: 20231215

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Synthesis and Additive Manufacturing of Hydrazone-Linked Covalent Organic Framework Aerogels.