Study of high temperature metal-insulator phase transition in La1−xCaxMnO3 employing in-situ ultrasonic studies.
In: Physica B, Jg. 456 (2015), S. 118-124
Online
academicJournal
Zugriff:
Bulk La 1− x Ca x MnO 3 ( x =0.70, 0.75 and 0.90) perovskite samples were synthesized using solid state reaction technique. X-ray diffraction study on the sample indicates that the sample has single phase orthorhombic structure with a space group of pnma and has no secondary phase. By employing through transmission technique operated at a fundamental frequency of 5 MHz, ultrasonic velocities and attenuation were measured for both longitudinal and shear waves over a wide range of temperature from 300 to 700 K. The ultrasonic parameters showed an anomalous behavior at the transition temperature 640, 560 and 370 K for x =0.70, 0.75 and 0.90, respectively. These anomalies in the ultrasonic parameters were used to explain the second order metal-insulator phase transition. The existence of the single-ion magnetostriction in LCMO perovskite manganites is also revealed from the ultrasonic measurements. [ABSTRACT FROM AUTHOR]
Titel: |
Study of high temperature metal-insulator phase transition in La1−xCaxMnO3 employing in-situ ultrasonic studies.
|
---|---|
Autor/in / Beteiligte Person: | Arunachalam, M. ; Thamilmaran, P. ; Sankarrajan, S. ; Sakthipandi, K. |
Link: | |
Zeitschrift: | Physica B, Jg. 456 (2015), S. 118-124 |
Veröffentlichung: | 2015 |
Medientyp: | academicJournal |
ISSN: | 0921-4526 (print) |
DOI: | 10.1016/j.physb.2014.08.033 |
Schlagwort: |
|
Sonstiges: |
|