Oxorhenium complexes with the 8-quinolinolato ligand. X-ray structure and DFT calculations for [ReOX<subscript>2</subscript>(hqn)(AsPh<subscript>3</subscript>)] and [ReOX<subscript>2</subscript>(hqn)(PPh<subscript>3</subscript>)] complexes
In: Polyhedron, Jg. 26 (2007-07-23), Heft 12, S. 2837-2844
Online
academicJournal
Zugriff:
Abstract: The reactions of [ReOX3(AsPh3)2] and [ReOX3(PPh3)2] with 8-hydroxyquinoline (Hhqn) have been examined and the complexes [ReOX2(hqn)(AsPh3)] and [ReOX2(hqn)(PPh3)] (X=Cl, Br) have been obtained, respectively. The crystal and molecular structures of [ReOCl2(hqn)(AsPh3)] (1) and [ReOBr2(hqn)(PPh3)] (4) have been determined. The electronic structure of 1 has been calculated with the density functional theory (DFT) method. The spin-allowed electronic transitions of 1 have been calculated with the time-dependent DFT method, and the UV–Vis spectrum of [ReOCl2(hqn)(AsPh3)] has been discussed on this basis. [Copyright &y& Elsevier]
Titel: |
Oxorhenium complexes with the 8-quinolinolato ligand. X-ray structure and DFT calculations for [ReOX<subscript>2</subscript>(hqn)(AsPh<subscript>3</subscript>)] and [ReOX<subscript>2</subscript>(hqn)(PPh<subscript>3</subscript>)] complexes
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Autor/in / Beteiligte Person: | Machura, B. ; Michalik, S. ; Kruszynski, R. ; Kusz, J. |
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Zeitschrift: | Polyhedron, Jg. 26 (2007-07-23), Heft 12, S. 2837-2844 |
Veröffentlichung: | 2007 |
Medientyp: | academicJournal |
ISSN: | 0277-5387 (print) |
DOI: | 10.1016/j.poly.2007.01.054 |
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