Functiaonalization of 2-(1-Cyclohexen-1-yl)aniline Derivatives.
In: Russian Journal of General Chemistry, Jg. 89 (2019-04-01), Heft 4, S. 653-662
Online
academicJournal
Zugriff:
The reaction of 2-(1-cyclohexen-1-yl)aniline and -6-methylaniline with phthalic anhydride has afforded 2-(2-cyclohex-1-en-1-ylphenyl)- and 2-(2-cyclohex-1-en-1-ylphenyl)-6-methylphenyl)-1H-isoindole-1,3(2H)-diones. The reaction of the obtained isoindole-1,3-diones with bromine in dichloromethane in the presence of sodium bicarbonate has led to the formation of the product of pseudo-allylic halogenation. Replacement of the halogen atom by methoxy group has been performed by keeping 2-[2-(6-bromocyclohex-1-en-1-ylphenyl)-6-methylphenyl)]-1H-isoindole-1,3(2H)-dione in a methanolic solution in the presence of NaHCO3. The reaction of 2-(2-cyclohex-1-en-1-yl-6-methylphenyl)-1H-isoindole-1,3(2H)-dione with molecular bromine in the presence of methanol has given a co-halogenation product, whereas the dibromination product has been obtained in the presence of octyl alcohol. [ABSTRACT FROM AUTHOR]
Titel: |
Functiaonalization of 2-(1-Cyclohexen-1-yl)aniline Derivatives.
|
---|---|
Autor/in / Beteiligte Person: | Khusnitdinov, R. N. ; Gataullin, R. R. ; Sultanov, R. M. |
Link: | |
Zeitschrift: | Russian Journal of General Chemistry, Jg. 89 (2019-04-01), Heft 4, S. 653-662 |
Veröffentlichung: | 2019 |
Medientyp: | academicJournal |
ISSN: | 1070-3632 (print) |
DOI: | 10.1134/S1070363219040030 |
Schlagwort: |
|
Sonstiges: |
|