Structure, Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents of (1 − x)Ba<subscript>0.6</subscript>Sr<subscript>0.4</subscript>La<subscript>4</subscript>Ti<subscript>4</subscript>O<subscript>15</subscript>- xBa<subscript>5</subscript>Nb<subscript>4</subscript>O<subscript>15</subscript> Solid Solutions.
In: Journal of the American Ceramic Society, Jg. 98 (2015-04-01), Heft 4, S. 1245-1252
Online
academicJournal
Zugriff:
(1 − x)Ba0.6Sr0.4La4Ti4O15- xBa5Nb4O15 ( x = 0.05, 0.1, 0.15 and 0.2, BSLT-BN) ceramic samples were prepared by co-firing the mixtures of Ba0.6Sr0.4La4Ti4O15 and Ba5Nb4O15 powders. Crystal structure, microwave dielectric properties and thermally stimulated depolarization currents (TSDC) of the BSLT-BN series ceramics were investigated. X-ray diffraction patterns reveal that all the samples exhibit a hexagonal perovskite structure, which implies that the BSLT-BN mixtures form solid solutions. With increasing Ba5Nb4O15 content, the diffraction peaks shift to low angles and the sintering temperature of BSLT-BN decreases. Raman spectra analysis reveals the shifting and splitting of the vibration modes. The microwave dielectric properties of the well-sintered (1 − x)BSLT- xBN ceramics vary with Ba5Nb4O15 content. The dielectric permittivity of the ceramics exhibits a slight decreasing trend. The quality factor varies in the range of 45 000-11 200 GHz, whereas near-zero temperature coefficients of the resonant frequency may be achieved by changing the Ba5Nb4O15 content. TSDC was utilized to explore the extrinsic loss mechanism associated with defects. TSDC relaxation peaks are mainly generated by oxygen vacancies, and the Ba5Nb4O15 content has a significant influence on the TSDC spectra. [ABSTRACT FROM AUTHOR]
Titel: |
Structure, Microwave Dielectric Properties and Thermally Stimulated Depolarization Currents of (1 − x)Ba<subscript>0.6</subscript>Sr<subscript>0.4</subscript>La<subscript>4</subscript>Ti<subscript>4</subscript>O<subscript>15</subscript>- xBa<subscript>5</subscript>Nb<subscript>4</subscript>O<subscript>15</subscript> Solid Solutions.
|
---|---|
Autor/in / Beteiligte Person: | Zhang, Xiaohua ; Zhang, Jie ; Xie, Zhenkun ; Yuan, Lixin ; Yue, Zhenxing ; Li, Longtu ; Tan, X. |
Link: | |
Zeitschrift: | Journal of the American Ceramic Society, Jg. 98 (2015-04-01), Heft 4, S. 1245-1252 |
Veröffentlichung: | 2015 |
Medientyp: | academicJournal |
ISSN: | 0002-7820 (print) |
DOI: | 10.1111/jace.13465 |
Schlagwort: |
|
Sonstiges: |
|